Analysis of Process Chemicals
ICP-MS is used routinely to test for trace metal impurities at the ppt level in the many organic and inorganic chemicals that are used in semiconductor processing and device manufacturing. These chemicals range from high-purity cleaning solvents (e.g., tetramethyl ammonium hydroxide and methanol) to complex organic mixtures (post-etch cleaners, photoresist, etc.) and highly volatile solvents such as acetone. Other important chemicals include: hydrofluoric acid, hydrochloric acid, sulfuric acid, hydrogen peroxide, isopropyl alcohol, and phosphoric acid.
Agilent’s solutions for process chemical analysis
The new 7700s ICP-MS is configured for the ultra-trace elemental analysis of high-purity materials such as process chemicals used in the semiconductor industry. With a high-efficiency sample introduction system, 5th plasma gas line (for option gas addition), and second (reaction) cell gas line as standard on the 3rd generation Octopole Reaction System (ORS3) – the 7700s offers the highest performance for the removal of intense interferences in known and consistent matrices.
With unmatched cool plasma capability, as well as unsurpassed collision/reaction cell performance, the 7700s delivers industry leading performance for the measurement of easily ionized elements (Li, Na, K, Fe and Ca) in high-purity materials, allowing all common semiconductor analytical methods to be performed on the same instrument.
Agilent also offers a clean Integrated Autosampler (I-AS) for ultra-trace analysis applications. The I-AS is a fast, flexible and high-precision autosampler designed to eliminate the risk of cross-sample contamination.
Literature
- Determination of Impurities in Semiconductor Grade Hydrochloric Acid Using the Agilent 7500cs ICP-MS
Junichi Takahashi, Agilent Technologies Agilent 7500 Series ICP-MS application note 5989-4348EN, Jan 2006
- Direct Analysis of NMP using a High Sensitivity Reaction Cell ICP-MS
Christopher T. Tye, Agilent Technologies Agilent 7500 Series ICP-MS technical feature 5988-9837EN, July, 2003
- Analysis of Impurities in Semiconductor Grade TMAH using the Agilent 7500cs ICP-MS
Junichi Takahashi and Kouichi Youno, Agilent Technologies Agilent 7500 Series ICP-MS application note 5988-9892EN, July, 2003
- Determination of Trace Metal Impurities in Semiconductor Grade Phosphoric Acid by High Sensitivity Reaction Cell ICP-MS
Junichi Takahashi and Kouichi Youno, Agilent Technologies Agilent 7500 Series ICP-MS application note 5988-8901EN, March, 2003
- Analysis of Impurities in Semiconductor Grade Sulfuric Acid using the Agilent 7500cs ICP-MS
Junichi Takahashi and Kouichi Youno, Agilent Technologies Agilent 7500 Series ICP-MS application note 5988-9190EN, April, 2003
- Determination of Trace Metal Impurities in Semiconductor-Grade Hydrogen Peroxide by ICP-MS
Abe G. Gutiérrez, Elemental Scientific, USA Junichi Takahashi and Tom Gluodenis, Agilent Technologies Agilent 7500 Series ICP-MS application note 5988-5947EN, April, 2002
- Determination of Trace Metal Impurities in Semiconductor-Grade Hydrofluoric Acid
Abe G. Gutiérrez, Elemental Scientific, USA Junichi Takahashi, Koichi Yono and Tom Gluodenis, Agilent Technologies Agilent 7500 Series ICP-MS application note 5988-5421EN, February 2002
- Applications of ICP-MS for Trace and Ultratrace Metal Quantitation in Organic Matrices
Ed McCurdy and Don Potter Agilent Technologies, UK Semiconductor International, October 2001
- Analysis of Semiconductor Grade Sulfuric Acid using the Agilent 7500s ICP-MS
Mike Radle and Tom Gluodenis Agilent Technologies Inc., USA Agilent 7500 Series ICP-MS application note 5988-3164EN, June 2001
- Testing of ICP-MS for the Routine Monitoring of Trace Metal Contamination (32 kbytes)
Iain Harrison and Frazer Tollan EKC Technology, Scotland, UK Courtesy of European Semiconductor, January 2001, pp.31-34
- Multi-element Analysis of N-methyl pyrrolidone by ICP-MS
Joe Hedrick Agilent Technologies Inc., USA Agilent 4500 Series ICP-MS application note 5965-8809EN, April 2000
- Examining purification and certification strategies for high-purity C2F6 process gas
Charles C. Allgood and Jeremy D. Blanks DuPont Fluoroproducts, Deepwater, NJ, USA Micro Magazine, April 1998
- Analyzing Semiconductor Grade Nitric Acid using the Agilent 7500
Rob Mortenson and James Thomas Ashland Chemical, Dublin Ohio, USA Agilent ICP-MS Journal, Issue 7, July, 2000
- Analysis of Organic Semiconductor Chemicals
Ed McCurdy, Agilent Technologies, UK ICP-MS Journal, Issue 5, November, 1999
- Sample Introduction Options for Semiconductor Chemical Analysis
Ed McCurdy, Agilent Technologies, UK ICP-MS Journal, Issue 5, November, 1999
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