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Gradient LC analysis of herbicides and polyaromatic hydrocarbons by isocratic Capillary Electrochromatography

Abstract: Capillary Electrochromatography (CEC) combines the separation principle of HPLC (partitioning between mobile and stationary phases) with the high efficiency of capillary electroseparation methods. In CEC the electroosmotic flow (EOF) inherent in capillary electrophoretic separations is used to transport solute and mobile phase through a packed capillary column. The properties of the EOF provides higher efficiencies than can be realized with L.C. This can be sufficient to allow the transfer of methods conventionally performed by gradient LC to be performed by isocratic CEC.


Keywords: Capillary Electrophoresis, CE, CEC, HPLC, gradient, herbicides, polyaromatic hydrocarbons, isocratic Capillary Electrochromatography, CEC, pesticides
Publication Number: 5965-9032E
Last Updated: 10/7/2009
Number of Pages: 2

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