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Highly sulphonated cyclodextrins for chiral analysis

Abstract: Capillary electrophoresis is ideally suited to the analysis of chiral solutes where the ease of method development and greatly reduced costs makes it an attractive alternative to liquid chromatography. Highly sulphonated cyclodextrins, used for chiral separations, have an associated high current which must be controlled in order that Joule heating does not unduly deteriorate the separation. By using small 25 μm id capillaries with an extended path length the Joule heating can be controlled while enhancing sensitivity.

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